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dc.contributor.authorFındık, Mükerrem
dc.contributor.authorUçar, Asuman
dc.contributor.authorÇolak, Alper Tolga
dc.contributor.authorŞahin, Onur
dc.contributor.authorBingöl, Haluk
dc.contributor.authorSayın, Ülkü
dc.contributor.authorKoçak, Nuriye
dc.date.accessioned2019-10-08T07:37:08Z
dc.date.available2019-10-08T07:37:08Z
dc.date.issued2019en_US
dc.identifier.citationFindik, M., Ucar, A., Colak, A. T., Sahin, O., Bingol, H., Sayin, U., & Kocak, N. (2019). Self-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blue. Polyhedron, 160, 229-237.en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.poly.2018.12.043
dc.identifier.urihttps://hdl.handle.net/20.500.12438/2431
dc.description.abstractA novel organic–inorganic hybrid of 2,2′-bipyridyl (2,2′-bipy) linked covalently with the first inorganic framework based on boron-containing Keggin-type heteropolymolybdate anion [BMo12O40]5− has been hydrothermally synthesized in aqueous solution. The crystal structure was fully characterized by elemental analyses, single crystal X-ray diffraction, Fourier-transform infrared spectrum (FT-IR), powder X-ray diffraction (XRD), Ultraviolet–visible spectroscopy (UV–Vis) and electron paramagnetic resonance (EPR) analysis. The catalytic performance of the synthesized catalyst was studied in degradation of methylene blue (MB) at ambient temperature. The catalyst exhibited excellent degradation against MB with a rate constant of 0.506/m, which was much higher than those by other polyoxometalate catalysts. Moreover, it was found to be easily separated from the reaction solution and recycled up to five times without significant loss of degradation activityen_US
dc.language.isoengen_US
dc.publisherElsevieren_US
dc.relation.isversionof10.1016/j.poly.2018.12.043en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPolyoxometalateen_US
dc.subjectHeteropolymolybdateen_US
dc.subjectCatalytic Degradationen_US
dc.subjectMethylene Blueen_US
dc.subjectSingle Crystal Structureen_US
dc.titleSelf-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blueen_US
dc.typearticleen_US
dc.relation.journalPolyhedronen_US
dc.departmentFen Edebiyat Fakültesien_US
dc.contributor.authorIDhttps://orcid.org/0000-0003-4478-7792en_US
dc.identifier.volume160en_US
dc.identifier.startpage229en_US
dc.identifier.endpage237en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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