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dc.contributor.authorŞen, Betül
dc.contributor.authorAygün, Ayşenur
dc.contributor.authorŞavk, Aysun
dc.contributor.authorGülbağça, Fulya
dc.contributor.authorGülbay, Senem Karahan
dc.contributor.authorÇalımlı, Mehmet Harbi
dc.contributor.authorŞen, Fatih
dc.date.accessioned2019-07-12T07:42:58Z
dc.date.available2019-07-12T07:42:58Z
dc.date.issued2019en_US
dc.identifier.citationŞen, B., Aygün, A., Şavk, A., Gülbağça, F., Gülbay, S. K., Çalımlı, M. H., & Şen, F. (2019). Binary Palladium–Nickel/Vulcan carbon-based nanoparticles as highly efficient catalyst for hydrogen evolution reaction at room temperature. Journal of the Taiwan Institute of Chemical Engineers, 101, 92-98.en_US
dc.identifier.urihttps://doi.org/10.1016/j.jtice.2019.04.040
dc.identifier.urihttps://hdl.handle.net/20.500.12438/571
dc.description.abstractHerein, Palladium–Nickel alloy nanoparticles assembled on Vulcan carbon composites (PdNi@VC) have been reported as highly efficient, stable and durable catalyst for the hydrogen evolution from dimethylamine borane. Palladium–Nickel alloy nanoparticles assembled on Vulcan carbon composites were prepared using ultrasonic reduction technique and characterized using some analytical methods. The characterization analyses revealed that Palladium–Nickel alloy nanoparticles assembled on Vulcan carbon composites have a monodisperse metal distribution and crystalline structure. Some catalytic experiments were performed, and some activation parameters such as activation energy (Ea=40.05 ± 2 kJ/mol), activation entropy (ΔS =−132.11± 1 J mol−1 K−1) and activation enthalpy (ΔH =37.55 ± 1 kJ mol−1) were calculated for catalytic reaction of dimethylamine borane. The turnover frequency (TOF) value of Palladium–Nickel alloy nanoparticles assembled on Vulcan carbon composites was found to be 283.48 h−1, having one of the best catalytic activities among the previous heterogenous catalysts tested for dimethylamine borane (DMAB) catalytic reaction. © 2019 Taiwan Institute of Chemical Engineersen_US
dc.language.isoengen_US
dc.publisherElsevieren_US
dc.relation.isversionof10.1016/j.jtice.2019.04.040en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCatalytic Reactionen_US
dc.subjectCharacterizationen_US
dc.subjectDimethylamine Boraneen_US
dc.subjectPdNi@VCen_US
dc.titleBinary Palladium–Nickel/Vulcan carbon-based nanoparticles as highly efficient catalyst for hydrogen evolution reaction at room temperatureen_US
dc.typearticleen_US
dc.relation.journalJournal of the Taiwan Institute of Chemical Engineersen_US
dc.departmentFen Edebiyat Fakültesien_US
dc.contributor.authorIDhttps://orcid.org/0000-0001-6843-9026en_US
dc.identifier.volume101en_US
dc.identifier.startpage92en_US
dc.identifier.endpage98en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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